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Electrical interference problems are complex and cannot be easily presented in this forum.  Noise,  pH or ORP offset voltage, optical isolation and solution earth, differential amplifiers, single ended amplifiers, amplifier input impedance > 1x1012 Ohms and much more make this a job for experts ... discuss your needs with the Ionode Tech Team.

Extracted from a previous case is the following informative discussion:

 .... the pH side of the probe develops a stable voltage between its output and the solution, which is dependent on the pH of the solution. The purpose of the Ag/AgCl reference then is to develop a stable voltage with respect to the solution, so you can complete the circuit and get the pH value. You can’t just use say a piece of metal as the reference because they develop a redox potential and the voltage isn’t stable. The way an ORP probe works is just that it measures the redox potential by having a piece of metal (typically platinum) in the solution, and it’s referenced to the Ag/AgCl reference in the probe.

Often in pools and industrial control applications a noise voltage develops between the solution and electrical earth. We assume that this happens because of poorly constructed pools, faulty pumps, or even static build up on the PVC pipes; however it's not something we or the controller manufacturer typically has control over and so we have to work around it.
The circuit diagrams should help explain the problem. The typical pH meter and electrode is shown in the 1st diagram. They use a single-ended amplifier for the pH signal. The pH electrode's reference is tied to the ground of the circuit, and so the voltage between them is assumed to be 0mV. When the ground of the pH circuit is otherwise untied, there is no problem, because it simply floats to the potential of the solution and there is no noise voltage applied across R_REFERENCE. For example, this is what happens when using a battery-powered handheld meter.


However, typical pool/control installations have a fixed power source which ties the ground potential to the same ground as the noise source, or another fixed potential with respect to the noise source. This in turn forces a noise voltage across R_REFERENCE which has a direct effect on the pH reading. Often the noise voltage is high enough to exceed the common mode input limits of the amplifier as well, causing it to saturate and even be damaged in some situations. In addition the extra current flowing through the electrode's reference polarises the reference giving another error source.
One solution to the problem is shown in the 2nd diagram. A differential instrumentation amplifier is used instead of the single-ended amplifier. The solution noise voltage is reduced to near 0 by the low resistance solution earth connector directly connected to the circuit ground; and the amplified voltage is now correctly the voltage between the pH and reference instead of the voltage between the pH and ground. Instrumentation amplifiers also typically have much better common mode rejection than traditional operational amplifier configurations.


Recommended is the TI INA116 instrumentation amplifier and other manufacturers also have amplifiers which are suitable. There are likely other techniques that solve the problem as well - for example one could design their own instrumentation amplifier; or use optical isolation. The key specifications for pH amplifiers are that the input impedance is much higher (typically 1000x) than the electrode resistance, so as a rule the input impedance should be greater than 1x1012 ohms (at 25C); and for the same reason the input bias current must be very low, as a rule less than 5pA (at 25C). Be aware that the resistance of a pH electrode doubles with every 6~10C drop in temperature and so lower temperatures require better performance from the amplifier.